全文获取类型
收费全文 | 52534篇 |
免费 | 3052篇 |
国内免费 | 2035篇 |
专业分类
化学 | 29858篇 |
晶体学 | 725篇 |
力学 | 2758篇 |
综合类 | 137篇 |
数学 | 5578篇 |
物理学 | 18565篇 |
出版年
2023年 | 376篇 |
2022年 | 575篇 |
2021年 | 821篇 |
2020年 | 920篇 |
2019年 | 950篇 |
2018年 | 1013篇 |
2017年 | 962篇 |
2016年 | 1426篇 |
2015年 | 1122篇 |
2014年 | 1600篇 |
2013年 | 2675篇 |
2012年 | 2964篇 |
2011年 | 3335篇 |
2010年 | 2360篇 |
2009年 | 2246篇 |
2008年 | 2590篇 |
2007年 | 2456篇 |
2006年 | 2341篇 |
2005年 | 1960篇 |
2004年 | 1717篇 |
2003年 | 1515篇 |
2002年 | 1463篇 |
2001年 | 1774篇 |
2000年 | 1286篇 |
1999年 | 1141篇 |
1998年 | 890篇 |
1997年 | 830篇 |
1996年 | 750篇 |
1995年 | 686篇 |
1994年 | 625篇 |
1993年 | 534篇 |
1992年 | 616篇 |
1991年 | 621篇 |
1990年 | 571篇 |
1989年 | 528篇 |
1988年 | 510篇 |
1987年 | 489篇 |
1986年 | 442篇 |
1985年 | 488篇 |
1984年 | 512篇 |
1983年 | 381篇 |
1982年 | 412篇 |
1981年 | 402篇 |
1980年 | 340篇 |
1979年 | 412篇 |
1978年 | 399篇 |
1977年 | 417篇 |
1976年 | 413篇 |
1975年 | 357篇 |
1973年 | 359篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
101.
V. Z. Kasimov O. V. Ushakova Yu. P. Khomenko 《Journal of Applied Mechanics and Technical Physics》2003,44(5):612-619
An improved procedure for modeling the operation of a light-gas gun is proposed. The motion of working bodies in both the firing chamber and the light-gas chamber is studied within the framework of the mechanics of heterogeneous media. The problem of barrel heating taking into account its melting and removal of thermal ablation products into the medium inside the bore is solved in a coupled formulation. Heat and mass transfer and friction on the barrel surface are calculated using empirical dependences. The deformable piston is considered compressible and elastoviscoplastic. Allowance is made for the presence of a clearance between the lateral surface of the piston and the barrel bore walls and the associated gas flow between the firing and the light-gas chamber. Calculation results are given. 相似文献
102.
Xiao Qi ZHENG Yong Hui WANG Qing Xiang GUO* Li YANG You Cheng LIU Department of Chemistry University of Science Technology of China Hefei National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2003,(8)
As artificial enzymes, the binding constants of cyclodextrins (CDs) and their substrates are expected to be high1. For this purpose, many kinds of bridged cyclodextrin dimers2 whose two cyclodextrins are linked by various spacers have been constructed. It was of interest to make the dimers, whose binding constants would exceed 108dm3/mol3. Up to date, the bridged cyclodextrin dimers have been extensively studied as enzyme models and as molecular receptors4-6. Recently, we synthesized a brid… 相似文献
103.
Mingbao Zhang Raymond Reeves Cheng Bi Robert Dally Gaetan Ladouceur William Bullock Jefferson Chin 《Tetrahedron letters》2004,45(27):5229-5231
Three novel, optically active, 6-substituted 2-(aminomethyl)chromans were synthesized from readily available chroman 2-carboxylic acid precursors. These chroman-containing primary amines are useful building blocks for the synthesis of chroman-derived pharmaceutical agents. 相似文献
104.
An experimental method is developed to examine the near tip deformation at the mesoscopic scale level. The differential interference contrast (DIC) method is used by application of the Nomarski prism in polarized microscope for measuring the out of surface deformation. The method is very sensitive to small height changes detected by different interference color. Discussed are results for the crack tip deformation field. 相似文献
105.
Teys S. A. Talochkin A. B. Romanyuk K. N. Olshanetsky B. Z. 《Physics of the Solid State》2004,46(1):80-84
Physics of the Solid State - The growth of germanium nanoislands and nanowires on singular and vicinal Si(111) surfaces is investigated by scanning tunneling microscopy (STM). It is shown that the... 相似文献
106.
107.
Yu. B. Bolkhovityanov S. Ts. Krivoshchapov A. I. Nikiforov B. Z. Ol’shanetskii O. P. Pchelyakov L. V. Sokolov S. A. Teys 《Physics of the Solid State》2004,46(1):64-66
Different techniques for the fabrication of structures containing ensembles of ultrasmall germanium nanoclusters distributed with a high density over the substrate surface are discussed. How to control the morphology and ordering of these ensembles is also discussed. 相似文献
108.
Zhaoqiang Lu Lin Cheng Jun Li Kai Zhang Song Yi Jingui Qin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):925-932
The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (SNAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl3, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 103 to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004 相似文献
109.
X. H. Li Y. Z. Meng S. J. Wang A. Varada Rajulu S. C. Tjong 《Journal of Polymer Science.Polymer Physics》2004,42(4):666-675
The composites of biodegradable poly(propylene carbonate) (PPC) reinforced with short Hildegardia populifolia natural fiber were prepared by melt mixing followed by compression molding. The mechanical properties, thermal properties, and morphologies of the composites were studied via static and dynamic mechanical measurements, thermogravimetric analysis, and scanning electron microscopy (SEM) techniques, respectively. Static tensile tests showed that the stiffness and tensile strength of the composites increased with an increasing fiber content. However, the elongation at break and the energy to break decreased dramatically with the addition of short fiber. The relationship between the experimental results and the compatibility or interaction between the PPC matrix and fiber was correlated. SEM observations indicated good interfacial contact between the short fiber and PPC matrix. Thermogravimetric analysis revealed that the introduction of short Hildegardia populifolia fiber led to a slightly improved thermooxidative stability of PPC. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 666–675, 2004 相似文献
110.
H. Kaczmarek J. Kowalonek Z. Klusek S. Pierzgalski S. Datta 《Journal of Polymer Science.Polymer Physics》2004,42(4):585-602
The photooxidative degradation of blends (in a full range of compositions) of amorphous poly(vinyl chloride) (PVC) with semicrystalline poly(ethylene oxide) (PEO) in the form of thin films is investigated using absorption spectroscopy (UV–visible and Fourier transform infrared) and atomic force microscopy (AFM). The amount of insoluble gel formed as a result of photocrosslinking is estimated gravimetrically. It is found that the PVC/PEO blendsí susceptibility to photooxidative degradation differs from that pure of the components and depends on the blend composition and morphology. Photoreactions such as degradation and oxidation are accelerated whereas dehydrochlorination is retarded in blends. The photocrosslinking efficiency in PVC/PEO blends is higher than in PVC; moreover, PEO is also involved in this process. AFM images showing the lamellar structure of semicrystalline PEO in the blend lead to the conclusion that the presence of PVC does not disturb the crystallization process of PEO. The changes induced by UV irradiation allow the observation of more of the distinct PEO crystallites. This is probably caused by recrystallization of short, more mobile chains in degraded PEO or by partial removal of the less stable amorphous phase from the film surface. These results confirm previous information on the miscibility of PVC with PEO. The mechanism of the interactions between the components and the blend photodegradation are discussed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 585–602, 2004 相似文献